57,321 research outputs found

    Removal of mercury (II) from aqueous solution by using rice residues

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    Sorption potential of rice residues for Hg(II) removal from aqueous solution was investigated. Rice husk (RH) and rice straw (RS) were selected and treated with sodium hydroxide (NaOH). The raw and modified adsorbents were characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR) and BET surface area measurements. The effects of pH, initial ion concentration, and agitation time on the removal process were studied in batch adsorption experiments. Two simple kinetic models, which are pseudo-first-order and pseudo-second-order, were tested to investigate the adsorption mechanisms. The kinetic data fits to pseudo second order model with correlation coefficients greater than 0.99 for all adsorbents. The equilibrium data fitted well with the Langmuir compared to Freundlich isotherm models. Alkali-treated adsorbent obtained larger surface area and RH-NaOH showed highest adsorption capacity followed by RS-Pure > RH-Pure > RS-NaOH. The maximum removal efficiency obtained by RH-NaOH and RS-Pure was 42 mg/l (80%) at pH 6.5 and with 2 days contact time (for 50 mg/l initial concentration and 25 mg adsorbents)

    Impurity scattering and Friedel oscillations in mono-layer black phosphorus

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    We study the effect of impurity scattering effect in black phosphorurene (BP) in this work. For single impurity, we calculate impurity induced local density of states (LDOS) in momentum space numerically based on tight-binding Hamiltonian. In real space, we calculate LDOS and Friedel oscillation analytically. LDOS shows strong anisotropy in BP. Many impurities in BP are investigated using TT-matrix approximation when the density is low. Midgap states appear in band gap with peaks in DOS. The peaks of midgap states are dependent on impurity potential. For finite positive potential, the impurity tends to bind negative charge carriers and vise versa. The infinite impurity potential problem is related to chiral symmetry in BP

    Liquid-liquid phase separation and morphology of internally mixed dicarboxylic acids/ammonium sulfate/water particles

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    Knowledge of the physical state and morphology of internally mixed organic/inorganic aerosol particles is still largely uncertain. To obtain more detailed information on liquid-liquid phase separation (LLPS) and morphology of the particles, we investigated complex mixtures of atmospherically relevant dicarboxylic acids containing 5, 6, and 7 carbon atoms (C5, C6 and C7) having oxygen-to-carbon atomic ratios (O:C) of 0.80, 0.67, and 0.57, respectively, mixed with ammonium sulfate (AS). With micrometer-sized particles of C5/AS/H_2O, C6/AS/H_2O and C7/AS/H_2O as model systems deposited on a hydrophobically coated substrate, laboratory experiments were conducted for various organic-to-inorganic dry mass ratios (OIR) using optical microscopy and Raman spectroscopy. When exposed to cycles of relative humidity (RH), each system showed significantly different phase transitions. While the C5/AS/H_2O particles showed no LLPS with OIR = 2:1, 1:1 and 1:4 down to 20% RH, the C6/AS/H_2O and C7/AS/H_2O particles exhibit LLPS upon drying at RH 50 to 85% and ~90%, respectively, via spinodal decomposition, growth of a second phase from the particle surface or nucleation-and-growth mechanisms depending on the OIR. This suggests that LLPS commonly occurs within the range of O:C < 0.7 in tropospheric organic/inorganic aerosols. To support the comparison and interpretation of the experimentally observed phase transitions, thermodynamic equilibrium calculations were performed with the AIOMFAC model. For the C7/AS/H_2O and C6/AS/H_2O systems, the calculated phase diagrams agree well with the observations while for the C5/AS/H_2O system LLPS is predicted by the model at RH below 60% and higher AS concentration, but was not observed in the experiments. Both core-shell structures and partially engulfed structures were observed for the investigated particles, suggesting that such morphologies might also exist in tropospheric aerosols

    VISHNU hybrid model for viscous QCD matter at RHIC and LHC energies

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    In this proceeding, we briefly describe the viscous hydrodynamics + hadron cascade hybrid model VISHNU for relativistic heavy ion collisions and report the current status on extracting the QGP viscosity from elliptic flow data.Comment: 4 pages, 1 figure, the proceedings of 7th International Workshop on Critical Point and Onset of Deconfinement, Wuhan, China, Nov. 7-11, 201

    Solar-neutrino reactions on deuteron in effective field theory

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    The cross sections for low-energy neutrino-deuteron reactions are calculated within heavy-baryon chiral perturbation theory employing cut-off regularization scheme. The transition operators are derived up to next-to-next-to-next-to-leading order in the Weinberg counting rules, while the nuclear matrix elements are evaluated using the wave functions generated by a high-quality phenomenological NN potential. With the adoption of the axial-current-four-nucleon coupling constant fixed from the tritium beta decay data, our calculation is free from unknown low-energy constants. Our results exhibit a high degree of stability against different choices of the cutoff parameter, a feature which indicates that, apart from radiative corrections, the uncertainties in the calculated cross sections are less than 1 %.Comment: 12 pages, 3 figures. Error estimation of higher order corrections detaile

    Pair loading in Gamma-Ray Burst Fireball And Prompt Emission From Pair-Rich Reverse Shock

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    Gamma-ray bursts (GRBs) are believed to originate from ultra-relativistic winds/fireballs to avoid the "compactness problem". However, the most energetic photons in GRBs may still suffer from γγ\gamma-\gamma absorption leading to electron/positron pair production in the winds/fireballs. We show here that in a wide range of model parameters, the resulting pairs may dominate those electrons associated with baryons. Later on, the pairs would be carried into a reverse shock so that a shocked pair-rich fireball may produce a strong flash at lower frequencies, i.e. in the IR band, in contrast with optical/UV emission from a pair-poor fireball. The IR emission would show a 5/2 spectral index due to strong self-absorption. Rapid responses to GRB triggers in the IR band would detect such strong flashes. The future detections of many IR flashes will infer that the rarity of prompt optical/UV emissions is in fact due to dust obscuration in the star formation regions.Comment: 8 pages, 2 figures, ApJ accepte
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